Sources of water as given Power Point

Boiler and cooling tower scaling is very expensive to control. The easiest control is no or minimal chemical control. The fewer chemicals you have to put into your boiler or cooling tower, the longer it will operate problem free and the the lower your costs will be. Using a pure water feed with minimal chemical additions, you will:

  • Minimize chemical costs
  • Greatly decrease the frequency of blowdown in your feed and bleed. For example: If your capacity is 1000 gallons and the feedwater is at 200 ppm, evaporating 50% and refilling, then blow down at 1200 ppm, you get about 10 cycles (each cycle adds 100 ppm). If you put 5 ppm in, you get 478 cycles (each cycle adds 2.5 ppm).

    If you purge 1000 gallons, per blowdown, that is a savings of 46,800 gallons over one 1200 PPM cycle!
  • Reduce maintenance and downtime
  • Extend boiler life
Boiler feedwater costs are associated with the following parameters
  • pH
  • Hardness
  • Oxygen and carbon dioxide concentration
  • Silicates
  • Dissolved solids
  • Suspended solids
  • Concentration organics
Remco systems can be utilized to minimize the need for other types of treatment and maintenance associated with these parameters. With the proper pretreatment, water discharge can be reduced to a small fraction of the present volume that will lower treatment costs.
Usual treatments include:
  • Water softening for hardness. Calcium and Magnesium (hardness ions) are removed by the softening process. Ca and Mg are exchanged for sodium ions on an ion exchange resin. Hardness in water causes scale. Scale is usually Calcium and/or Magnesium carbonate that precipitates out as the ions are concentrated in the boiler. Chemicals can be added to control scale but they can be reduced to a very small quantity if a softener is used.
  • Pervaporation, a membrane process or deaerator can be used to remove Oxygen and CO2 down to very low levels for high pressure boilers. Only small amounts of chemical oxygen scavengers are required after oxygen removal.
  • Silicates cause another type of scaling and can be removed with ion exchange or a membrane process. Membrane systems are preferred where dissolved ion concentrations are high because of operating cost considerations. High silicate levels are difficult and may require co-precipitation with other ions or high temperature caustic regeneration of ion exchange system.
  • Dissolved solids can be removed by ion exchange or Reverse Osmosis membrane processes. The results are similar with ion exchange able to remove practically all the ions and RO able to get very close with lower operating and maintenance costs. With high TDS concentrating, a combination of the two can be very cost effective. The advantage of removing dissolved solids is that you can greatly increase the time between blowdowns as the makeup water is almost void of solids. It takes much longer to get to the concentration when the boiler should be blown.
  • Suspended solids are removed by filtration. Normally, you would want a backwashing filter followed by a fine cartridge filter for the best results. The backwashing filter can take high solids loading before flows are reduced and is self cleaning. The polishing filter makes sure any residual material does not get through.
  • Concentration of organics are less of a problem in a properly designed feedwater system because much less chemistry is required to maintain the boiler. It is much easier to balance the system, and in some systems, no oxygen scavenger is required.

Remember, a good water analysis is you best friend. We will ask you for a water analysis. Print out the attached form if you don't know what you need to measure.

Boiler Water Quality Links:

Boiler Water Treatment: Lessons Learned (US Army)

Minimize Boiler Blow down

Improving Steam System Performance: A Sourcebook for Industry

Steam Handbook: Chapter 2, Water Treatment

As it is seen from the above diagram only 3.0% of earths water is fresh water. Out of this only 30.1 % & 0.3 % is useable.

No water, irrespective of the original source, should be assumed to be completely free of contamination & pollution. These contaminations may be natural or man made. The common contaminations, impurities & pollution in water are odor, tastes, colour, turbidity, suspended solids, organic and inorganic pollutants like pesticides, insecticides, herbicides, VOCs, dissolved gases, dissolved solids, heavy metals, domestic, chemical & industrial waste, bacteria, virus, Water Treatment is a Physical & Chemical process for making water suitable for human consumption and other processes.

As contaminations and pollutions of water are different, treatment required depend upon nature of contamination. Most of the times combinations of treatment technologies are used to treat water.

Water purification is the process where microbiological contamination is controlled. Again various technologies are used for water purification.

Application areas where water & water treatment is required :

Human consumption :
Drinking, cooking, bathing, washing, cleaning etc.

Process Industries :
Package drinking water plants, Food, hotel, medicine, pharmaceutical, laundry, cooling towers, boilers, swimming pool, molding machines, different manufacturing units, aqua cultures, construction, etc.

Different Technologies used as Water Treatment & Purifications :
Sedimentation, Coagulation, filtration, activated carbon, chemical disinfection, conditioning, softening, ion exchange, ultra violet, reverse osmosis, ozonation,

 
List of Contaminants & their MCL :
  • Microorganisms
  • Disinfectants
  • Disinfection Byproducts
  • Inorganic Chemicals
  • Organic Chemicals
  • Radionuclides
 
Microorganisms
 
Contaminant MCLG1
(mg/L)2
MCL or TT1
(mg/L)2
Potential Health Effects from Ingestion of Water Sources of Contaminant in Drinking Water
Cryptosporidium (pdf file) zero TT 3 Gastrointestinal illness (e.g., diarrhea, vomiting, cramps)
 
Human and fecal animal waste
Giardia lamblia zero TT 3 Gastrointestinal illness (e.g., diarrhea, vomiting, cramps) Human and animal fecal waste
Heterotrophic plate count n/a TT 3 HPC has no health effects; it is an analytic method used to measure the variety of bacteria that are common in water. The lower the concentration of bacteria in drinking water, the better maintained the water system is. HPC measures a range of bacteria that are naturally present in the environment
Legionella zero TT 3 Legionnaire's Disease, a type of pneumonia Found naturally in water; multiplies in heating systems
Total Coliforms (including fecal coliform and E. Coli) zero 5.0%4
 
Not a health threat in itself; it is used to indicate whether other potentially harmful bacteria may be present5 Coliforms are naturally present in the environment; as well as feces; fecal coliforms and E. coli only come from human and animal fecal waste.
Turbidity n/a TT3 Turbidity is a measure of the cloudiness of water. It is used to indicate water quality and filtration effectiveness (e.g., whether disease-causing organisms are present). Higher turbidity levels are often associated with higher levels of disease-causing microorganisms such as viruses, parasites and some bacteria. These organisms can cause symptoms such as nausea, cramps, diarrhea, and associated headaches. Soil runoff
Viruses (enteric) zero TT3 Gastrointestinal illness (e.g., diarrhea, vomiting, cramps) Human and animal fecal waste
 
Disinfectants
 
Contaminant MRDLG1
(mg/L)2
MRDL1
(mg/L)2
Potential Health Effects from Ingestion of Water Sources of Contaminant in Drinking Water
Chloramines (as Cl2)
 
MRDLG=41 MRDL=4.01 Eye/nose irritation; stomach discomfort, anemia Water additive used to control microbes
 
Chlorine (as Cl2) MRDLG=41 MRDL=4.01 Eye/nose irritation; stomach discomfort Water additive used to control microbes
Chlorine dioxide (as ClO2) MRDLG=0.81 MRDL=0.81 Anemia; infants & young children: nervous system effects Water additive used to control microbes
 
 
Disinfection Byproducts
 
Contaminant MCLG1
(mg/L)2
MCL or TT1
(mg/L)2
Potential Health Effects from Ingestion of Water Sources of Contaminant in Drinking Water
Bromate zero 0.010 Increased risk of cancer Byproduct of drinking water disinfection
Chlorite 0.8 1.0 Anemia; infants & young children: nervous system effects Byproduct of drinking water disinfection
Haloacetic acids (HAA5) n/a6 0.060 Increased risk of cancer Byproduct of drinking water disinfection
Total Trihalomethanes (TTHMs) none7
-----
n/a6
0.10
-----
-
0.080
Liver, kidney or central nervous system problems; increased risk of cancer Byproduct of drinking water disinfection
 
Inorganic Chemicals
 
Contaminant MCLG1
(mg/L)2
MCL or TT1
(mg/L)2
Potential Health Effects from Ingestion of Water Sources of Contaminant in Drinking Water
Antimony 0.006 0.006 Increase in blood cholesterol; decrease in blood sugar Discharge from petroleum refineries; fire retardants; ceramics; electronics; solder
Arsenic 07 0.010
as of 01/23/06
Skin damage or problems with circulatory systems, and may have increased risk of getting cancer Erosion of natural deposits; runoff from orchards, runoff from glass & electronicsproduction wastes
Asbestos
(fiber >10 micrometers)
7 million fibers per liter 7 MFL Increased risk of developing benign intestinal polyps Decay of asbestos cement in water mains; erosion of natural deposits
Barium 2 2 Increase in blood pressure Discharge of drilling wastes; discharge from metal refineries; erosion of natural deposits
Beryllium 0.004 0.004 Intestinal lesions Discharge from metal refineries and coal-burning factories; discharge from electrical, aerospace, and defense industries
Cadmium 0.005 0.005 Kidney damage Corrosion of galvanized pipes; erosion of natural deposits; discharge from metal refineries; runoff from waste batteries and paints
Chromium (total) 0.1 0.1 Allergic dermatitis Discharge from steel and pulp mills; erosion of natural deposits
Copper 1.3 TT8;
Action Level=1.3
Short term exposure: Gastrointestinal distress

Long term exposure: Liver or kidney damage

People with Wilson's Disease should consult their personal doctor if the amount of copper in their water exceeds the action level
Corrosion of household plumbing systems; erosion of natural deposits
Cyanide (as free cyanide) 0.2 0.2 Nerve damage or thyroid problems Discharge from steel/metal factories; discharge from plastic and fertilizer factories
Fluoride 4.0 4.0 Bone disease (pain and tenderness of the bones); Children may get mottled teeth Water additive which promotes strong teeth; erosion of natural deposits; discharge from fertilizer and aluminum factories
Lead zero TT8;
Action Level=0.015
Infants and children: Delays in physical or mental development; children could show slight deficits in attention span and learning abilities

Adults: Kidney problems; high blood pressure
Corrosion of household plumbing systems; erosion of natural deposits
Mercury (inorganic) 0.002 0.002 Kidney damage Erosion of natural deposits; discharge from refineries and factories; runoff from landfills and croplands
Nitrate (measured as Nitrogen) 10 10 Infants below the age of six months who drink water containing nitrate in excess of the MCL could become seriously ill and, if untreated, may die. Symptoms include shortness of breath and blue-baby syndrome. Runoff from fertilizer use; leaching from septic tanks, sewage; erosion of natural deposits
Nitrite (measured as Nitrogen) 1 1 Infants below the age of six months who drink water containing nitrite in excess of the MCL could become seriously ill and, if untreated, may die. Symptoms include shortness of breath and blue-baby syndrome. Runoff from fertilizer use; leaching from septic tanks, sewage; erosion of natural deposits
Selenium 0.05 0.05 Hair or fingernail loss; numbness in fingers or toes; circulatory problems Discharge from petroleum refineries; erosion of natural deposits; discharge from mines
Thallium 0.0005 0.002 Hair loss; changes in blood; kidney, intestine, or liver problems Leaching from ore-processing sites; discharge from electronics, glass, and drug factories
 
 
Organic Chemicals
 
Contaminant MCLG1
(mg/L)2
MCL or TT1
(mg/L)2
Potential Health Effects from Ingestion of Water Sources of Contaminant in Drinking Water
Acrylamide zero TT9 Nervous system or blood problems; increased risk of cancer Added to water during sewage/wastewater treatment
Alachlor zero 0.002 Eye, liver, kidney or spleen problems; anemia; increased risk of cancer Runoff from herbicide used on row crops
Atrazine 0.003 0.003 Cardiovascular system or reproductive problems Runoff from herbicide used on row crops
Benzene zero 0.005 Anemia; decrease in blood platelets; increased risk of cancer Discharge from factories; leaching from gas storage tanks and landfills
Benzo(a)pyrene (PAHs) zero 0.0002 Reproductive difficulties; increased risk of cancer Leaching from linings of water storage tanks and distribution lines
Carbofuran 0.04 0.04 Problems with blood, nervous system, or reproductive system Leaching of soil fumigant used on rice and alfalfa
Carbon
tetrachloride
zero 0.005 Liver problems; increased risk of cancer Discharge from chemical plants and other industrial activities
Chlordane zero 0.002 Liver or nervous system problems; increased risk of cancer Residue of banned termiticide
Chlorobenzene 0.1 0.1 Liver or kidney problems Discharge from chemical and agricultural chemical factories
2,4-D 0.07 0.07 Kidney, liver, or adrenal gland problems Runoff from herbicide used on row crops
Dalapon 0.2 0.2 Minor kidney changes Runoff from herbicide used on rights of way
1,2-Dibromo-3-chloropropane (DBCP) zero 0.0002 Reproductive difficulties; increased risk of cancer Runoff/leaching from soil fumigant used on soybeans, cotton, pineapples, and orchards
o-Dichlorobenzene 0.6 0.6 Liver, kidney, or circulatory system problems Discharge from industrial chemical factories
p-Dichlorobenzene 0.075 0.075 Anemia; liver, kidney or spleen damage; changes in blood Discharge from industrial chemical factories
1,2-Dichloroethane zero 0.005 Increased risk of cancer Discharge from industrial chemical factories
1,1-Dichloroethylene 0.007
0.007
Liver problems Discharge from industrial chemical factories
cis-1,2-Dichloroethylene 0.07 0.07 Liver problems Discharge from industrial chemical factories
trans-1,2-Dichloroethylene 0.1 0.1 Liver problems Discharge from industrial chemical factories
Dichloromethane zero 0.005 Liver problems; increased risk of cancer Discharge from drug and chemical factories
1,2-Dichloropropane zero 0.005 Increased risk of cancer Discharge from industrial chemical factories
Di(2-ethylhexyl) adipate 0.4 0.4 Weight loss, liver problems, or possible reproductive difficulties. Discharge from chemical factories
Di(2-ethylhexyl) phthalate zero 0.006 Reproductive difficulties; liver problems; increased risk of cancer Discharge from rubber and chemical factories
Dinoseb 0.007 0.007 Reproductive difficulties Runoff from herbicide used on soybeans and vegetables
Dioxin (2,3,7,8-TCDD) zero 0.00000003 Reproductive difficulties; increased risk of cancer Emissions from waste incineration and other combustion; discharge from chemical factories
Diquat 0.02 0.02 Cataracts Runoff from herbicide use
Endothall 0.1 0.1 Stomach and intestinal problems Runoff from herbicide use
Endrin 0.002 0.002 Liver problems Residue of banned insecticide
Epichlorohydrin zero TT9 Increased cancer risk, and over a long period of time, stomach problems Discharge from industrial chemical factories; an impurity of some water treatment chemicals
Ethylbenzene 0.7 0.7 Liver or kidneys problems Discharge from petroleum refineries
Ethylene dibromide zero 0.00005 Problems with liver, stomach, reproductive system, or kidneys; increased risk of cancer Discharge from petroleum refineries
Glyphosate 0.7 0.7 Kidney problems; reproductive difficulties Runoff from herbicide use
Heptachlor zero 0.0004 Liver damage; increased risk of cancer Residue of banned termiticide
Heptachlor epoxide zero 0.0002 Liver damage; increased risk of cancer Breakdown of heptachlor
Hexachlorobenzene zero 0.001 Liver or kidney problems; reproductive difficulties; increased risk of cancer Discharge from metal refineries and agricultural chemical factories
Hexachlorocyclopentadiene 0.05 0.05 Kidney or stomach problems Discharge from chemical factories
Lindane 0.0002 0.0002 Liver or kidney problems Runoff/leaching from insecticide used on cattle, lumber, gardens
Methoxychlor 0.04 0.04 Reproductive difficulties Runoff/leaching from insecticide used on fruits, vegetables, alfalfa, livestock
Oxamyl (Vydate) 0.2 0.2 Slight nervous system effects Runoff/leaching from insecticide used on apples, potatoes, and tomatoes
Polychlorinated
biphenyls (PCBs)
zero 0.0005 Skin changes; thymus gland problems; immune deficiencies; reproductive or nervous systemdifficulties; increased risk of cancer Runoff from landfills; discharge of waste chemicals
Pentachlorophenol zero 0.001 Liver or kidney problems; increased cancer risk Discharge from wood preserving factories
Picloram 0.5 0.5 Liver problems Herbicide runoff
Simazine 0.004 0.004 Problems with blood Herbicide runoff
Styrene 0.1 0.1 Liver, kidney, or circulatory system problems
Discharge from rubber and plastic factories; leaching from landfills
Tetrachloroethylene zero 0.005 Liver problems; increased risk of cancer Discharge from factories and dry cleaners
Toluene 1 1 Nervous system, kidney, or liver problems Discharge from petroleum factories
Toxaphene zero 0.003 Kidney, liver, or thyroid problems; increased risk of cancer Runoff/leaching from insecticide used on cotton and cattle
2,4,5-TP (Silvex) 0.05 0.05 Liver problems Residue of banned herbicide
1,2,4-Trichlorobenzene 0.07 0.07 Changes in adrenal glands Discharge from textile finishing factories
1,1,1-Trichloroethane 0.20 0.2 Liver, nervous system, or circulatory problems Discharge from metal degreasing sites and other factories
1,1,2-Trichloroethane 0.003 0.005 Liver, kidney, or immune system problems Discharge from industrial chemical factories
Trichloroethylene zero 0.005 Liver problems; increased risk of cancer Discharge from metal degreasing sites and other factories
Vinyl chloride zero 0.002 Increased risk of cancer Leaching from PVC pipes; discharge from plastic factories
Xylenes (total) 10 10 Nervous system damage Discharge from petroleum factories; discharge from chemical factories
 
Radionuclides
 
Contaminant MCLG1
(mg/L)2
MCL or TT1
(mg/L)2
Potential Health Effects from Ingestion of Water Sources of Contaminant in Drinking Water
Alpha particles none7
-----
zero
15 picocuries per Liter (pCi/L) Increased risk of cancer Erosion of natural deposits of certain minerals that are radioactive and may emit a form of radiation known as alpha radiation
Beta particles and photon emitters none7
-----
zero
4 millirems per year Increased risk of cancer Decay of natural and man-made deposits of certain minerals that are radioactive and may emit forms of radiation known as photons and beta radiation
Radium 226 and Radium 228 (combined) none7
-----
zero
5 pCi/L Increased risk of cancer Erosion of natural deposits
Uranium zero 30 ug/L
as of 12/08/03
Increased risk of cancer, kidney toxicity Erosion of natural deposits
Notes

Definitions:
Maximum Contaminant Level (MCL) - The highest level of a contaminant that is allowed in drinking water. MCLs are set as close to MCLGs as feasible using the best available treatment technology and taking cost into consideration. MCLs are enforceable standards.
Maximum Contaminant Level Goal (MCLG) - The level of a contaminant in drinking water below which there is no known or expected risk to health. MCLGs allow for a margin of safety and are non-enforceable public health goals.
Maximum Residual Disinfectant Level (MRDL) - The highest level of a disinfectant allowed in drinking water. There is convincing evidence that addition of a disinfectant is necessary for control of microbial contaminants.
Maximum Residual Disinfectant Level Goal (MRDLG) - The level of a drinking water disinfectant below which there is no known or expected risk to health. MRDLGs do not reflect the benefits of the use of disinfectants to control microbial contaminants.
Treatment Technique - A required process intended to reduce the level of a contaminant in drinking water.


Units are in milligrams per liter (mg/L) unless otherwise noted. Milligrams per liter are equivalent to parts per million.


EPA's surface water treatment rules require systems using surface water or ground water under the direct influence of surface water to (1) disinfect their water, and (2) filter their water or meet criteria for avoiding filtration so that the following contaminants are controlled at the following levels:
• Cryptosporidium: (as of1/1/02 for systems serving >10,000 and 1/14/05 for systems serving <10,000) 99% removal.
• Giardia lamblia: 99.9% removal/inactivation
• Viruses: 99.99% removal/inactivation
•Legionella: No limit, but EPA believes that if Giardia and viruses are removed/inactivated, Legionella will also be controlled.
• Turbidity: At no time can turbidity (cloudiness of water) go above 5 nephelolometric turbidity units (NTU); systems that filter must ensure that the turbidity go no higher than 1 NTU (0.5 NTU for conventional or direct filtration) in at least 95% of the daily samples in any month. As of January 1, 2002, turbidity may never exceed 1 NTU, and must not exceed 0.3 NTU in 95% of daily samples in any month.
• HPC: No more than 500 bacterial colonies per milliliter.
• Long Term 1 Enhanced Surface Water Treatment (Effective Date: January 14, 2005); Surface water systems or (GWUDI) systems serving fewer than 10,000 people must comply with the applicable Long Term 1 Enhanced Surface Water Treatment Rule provisions (e.g. turbidity standards, individual filter monitoring, Cryptosporidium removal requirements, updated watershed control requirements for unfiltered systems).
• Filter Backwash Recycling; The Filter Backwash Recycling Rule requires systems that recycle to return specific recycle flows through all processes of the system's existing conventional or direct filtration system or at an alternate location approved by the state.


More than 5.0% samples total coliform-positive in a month. (For water systems that collect fewer than 40 routine samples per month, no more than one sample can be total coliform-positive per month.) Every sample that has total coliform must be analyzed for either fecal coliforms or E. coli if two consecutive TC-positive samples, and one is also positive for E.coli fecal coliforms, system has an acute MCL violation.


Fecal coliform and E. coli are bacteria whose presence indicates that the water may be contaminated with human or animal wastes. Disease-causing microbes (pathogens) in these wastes can cause diarrhea, cramps, nausea, headaches, or other symptoms. These pathogens may pose a special health risk for infants, young children, and people with severely compromised immune systems.


Although there is no collective MCLG for this contaminant group, there are individual MCLGs for some of the individual contaminants:

•  Trihalomethanes: bromodichloromethane (zero); bromoform (zero); dibromochloromethane (0.06 mg/L). Chloroform is regulated with this group but has no MCLG.

•  Haloacetic acids: dichloroacetic acid (zero); trichloroacetic acid (0.3 mg/L). Monochloroacetic acid, bromoacetic acid, and dibromoacetic acid are regulated with this group but have no MCLGs.


MCLGs were not established before the 1986 Amendments to the Safe Drinking Water Act. Therefore, there is no MCLG for this contaminant.


Lead and copper are regulated by a Treatment Technique that requires systems to control the corrosiveness of their water. If more than 10% of tap water samples exceed the action level, water systems must take additional steps. For copper, the action level is 1.3 mg/L, and for lead is 0.015 mg/L.


Each water system must certify, in writing, to the state (using third-party or manufacturer's certification) that when acrylamide and epichlorohydrin are used in drinking water systems, the combination (or product) of dose and monomer level does not exceed the levels specified, as follows:

• Acrylamide = 0.05% dosed at 1 mg/L (or equivalent)
• Epichlorohydrin = 0.01% dosed at 20 mg/L (or equivalent)

 
 
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